Q1.At a particular temperature and atmospheric pressure, the solid and liquid phases of a pure substance can exist in equilibrium. Which of the following term defines this temperature?
Answer : Option BExplaination / Solution:
Normal melting both the phases liquid and solid exist in equilibrium.
Q2.The aqueous solution of sugar does not conduct electricity. However, when sodium chloride is added to water, it conducts electricity. How will you explain this statement on the basis of ionisation and how is it affected by concentration of sodium chloride?
Answer : Option AExplaination / Solution:
NaCl ionises completely in water and increase in concentration of salt increases conductance.
Q3.BF3does not have proton but still acts as an acid and reacts with NH3. Why is it so? What type of bond is formed between the two?
Answer : Option BExplaination / Solution: BF3 is a Lewis acid as B has its vacant p orbital and coordinate bond is formed as NH3 donates its lp of electrons to the vacant orbital of B.
The ionization constant of acetic acid is1.74 x 10−5 . Calculate the degree of dissociation of acetic acid in its 0.05 M solution. Calculate the concentration of acetate ion in the solution and its pH.
Answer : Option BExplaination / Solution: Ka =Cα2 and pH=-log(Cα).
Q7.It has been found that the pH of a 0.01M solution of an organic acid is 4.15.Calculate the concentration of the anion, the ionization constant of the acid and its pKa
Answer : Option DExplaination / Solution: Ka =Cα2 and pH=-log(Cα) and pKa=-logKa
A vessel at 1000 K contains CO2with a pressure of 0.5 atm. Some of the CO2 is converted into CO on the addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is