Coordination Compounds - Online Test

Q1. Lithiumtetrahydridoaluminate is represented as
Answer : Option A
Explaination / Solution:

Lithiumtetrahydridoaluminate is Li[AlH4]
Q2. The correct name of the compound [Cu(NH3)4](NO3)2is
Answer : Option C
Explaination / Solution:

Tetraamminecopper(II)nitrate is [Cu(NH3)4](NO3)2
Q3. Which of the following compound would exhibit coordination isomerism?
Answer : Option D
Explaination / Solution:

Coordination isomerism is exhibited the the compounds in which cationic and anionic species is coordination complex.

Q4. The kind of isomerism exhibited by [Rh(en)2Cl2][Ir(en)Cl4] and [Ir(en)3][RhCl6] is
Answer : Option D
Explaination / Solution:

There is exchange of ligands between the cationic and anion species in coordination sphere.

Q5. The complex with highest stability constant at 298K is
Answer : Option B
Explaination / Solution:

Stability is proportional to CFSE value which is dependent upon Δo value. CN is stronger field which increases the CFSE.
Q6. Which of the following complex ions/molecules of nickel is paramagnetic?
Answer : Option A
Explaination / Solution:

Ni2+ is in 3d8 configuration so its para magnetic .
Q7. The compound [Cr(H2O)6]Cl3 and [Cr(H2O)4Cl2]Cl.2H2O represent
Answer : Option B
Explaination / Solution:

There is exchange of 4H_2O$ molecules inside and outside the coordination sphere.

Q8. Which isomerism is exhibited by the compound [Co(NH3)3(H2O)3]Cl3?
Answer : Option A
Explaination / Solution:

Complex of type [ Ma3b3] show geometrical isomerism.
Q9. The tetrahedral complex, bis(benzoylacetonato)beryllium(II) will show
Answer : Option C
Explaination / Solution:

This complex is non superimposable mirror image.

Q10. Which of the following complexes can form d and l isomers?
Answer : Option B
Explaination / Solution:

Cis  [Co(en)2Cl2]+exist as non superimposable mirror image.